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Ammonia as a Carbon-Free Energy Carrier

Introduction

Ammonia (NH₃) is considered a promising carbon-free energy carrier, but its energy-intensive production process remains a challenge for global scientists. A research team led by City University of Hong Kong (CityU) has recently engineered a bimetallic alloy as an ultrathin nanocatalyst that can greatly improve electrochemical performance for generating ammonia from nitrate (NO₃^–), offering great potential for obtaining carbon-neutral fuel in the future.

Interest in Ammonia

Ammonia, commonly used in fertilizer, has garnered attention due to its potential as a source of hydrogen for fuel cells and its ease of liquefaction and transportation. Given its high demand, upcycling nitrate (NO₃^–) from ammonium fertilizer-polluted wastewater has emerged as an alternative for reproducing valuable ammonia and making agriculture more sustainable.

Challenges and Solutions

The electrochemical reduction reaction of nitrate (NO₃RR) is seen as a promising solution for ammonia synthesis. However, the undesired by-products and the competing hydrogen evolution reaction (HER) during NO₃RR inhibit the yield rate of ammonia production. Professor Fan Zhanxi and his team at CityU addressed this challenge by engineering a novel bimetallic alloy electrocatalyst, called RuFe nanoflowers, which demonstrated significantly better electrochemical performance for ammonia production.

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Conclusion

This groundbreaking research at CityU opens up new possibilities for next-generation electrochemical energy systems, offering potential for sustainable nitrogen cycle and carbon-free energy in the future. The study’s findings were published in the Proceedings of the National Academy of Sciences (PNAS) under the title ÔÇ£Atomic coordination environment engineering of bimetallic alloy nanostructures for efficient ammonia electrosynthesis from nitrateÔÇØ.

The research was supported by the National Natural Science Foundation of China, the Hong Kong Research Grants Council, the Innovation and Technology Commission, and CityU.

For more information, visit: CityU Research – Bimetallic Alloy Nanocatalyst

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